Search results for "dependence [isospin]"
showing 10 items of 30 documents
Nitrogen broadening of SF6 transitions in the nu3 band
2001
Abstract Nitrogen induced pressure-broadened halfwidths of a number of ν3 transitions of SF6 are calculated using the complex Robert–Bonamy (CRB) formalism. The calculations are made at 200, 250, 296 and 350 K and the temperature dependence of the halfwidths are determined. The intermolecular potential is taken as a sum of the leading electrostatic and Lennard-Jones [6] , [7] , [8] , [9] , [10] , [11] , [12] atom–atom components. The dynamics of the collision process are correct to second order in time. The calculated halfwidths are used to simulate the ν3 spectrum, which is compared to a simulation made using the HITRAN96 halfwidths and measurements made at the Universite Pierre et Marie C…
Guía para la incorporación de la perspectiva de género en la docencia en Sociología, Economía y Ciencias Políticas
2019
Sociology has constructed a male worldview that entails a biased interpretation of social reality. For its part, the traditional economy has made invisible the dependence of the commercial sphere of the domestic sphere. And in the field of political science, we also find many gender biases in basic concepts such as justice, equality or citizenship. This article, based on the work done by the authors in the Guia per a una docència universitària amb perspectiva de gènere de Sociologia, Economia i Ciència Política, offers some proposals, teaching resources and consultation tools to introduce the gender perspective in teaching, knowledge transfer and research in these disciplines.
Modeling S-carboxymethyl-L-cysteine protonation and activity coefficients in sodium and tetramethylammonium chloride aqueous solutions by SIT and Pit…
2007
Solubility and acid–base properties of S-carboxymethyl-l-cysteine (carbocysteine, ccys) in NaClaq and tetramethylammonium chloride, (CH3)4NClaq ,a tt =2 5 ◦ C and at different ionic strengths were investigated. Solubility was studied at 1.0 ≤ I (mol L −1 ) ≤ 5.0 for NaClaq and 1.0 ≤ I (mol L −1 ) ≤ 3.0 for (CH3)4NClaq, while potentiometric measurements (by ISE-H + , glass electrode) were performed at 0.1 ≤ I (mol L −1 ) ≤ 5.0 for NaClaq and 0.5 ≤ I (mol L −1 ) ≤ 3.0 for (CH3)4NClaq. Solubility data allowed us to determine Setschenow constants and activity coefficients of neutral carbocysteine (H2ccys). Dependence on ionic strength and ionic medium of protonation constants and activity coeff…
Hydrolysis and chemical speciation of dioxouranium(VI) ion in aqueous media simulating the major ion composition of seawater
2004
Abstract The hydrolysis and chemical speciation of the dioxouranium(VI) ion at 25 °C was studied in a number of binary electrolytes (LiCl, NaCl, MgCl2, CaCl2, Na2SO4) and some mixtures (NaCl–Na2SO4, NaNO3–Na2SO4, CaCl2–MgCl2) as well as artificial seawater (SSWE) as a function of ionic strength. The results in LiCl, CaCl2 and MgCl2 solutions confirmed the formation of (UO2)2(OH)22+, (UO2)3(OH)42+, (UO2)3(OH)5+ and (UO2)3(OH)7− species (at I=0 mol l−1: log Tβ22=−5.76, log Tβ34=−11.82, log Tβ35=−15.89 and log Tβ37=−29.26). For NaNO3, NaCl and artificial seawater the hydrolysis constant for the formation of the UO2(OH)+ species was also determined (at I=0 mol l−1: log Tβ11=−5.19). The results …
Modeling ATP protonation and activity coefficients in NaClaq and KClaq by SIT and Pitzer equations.
2006
Abstract The acid–base properties of Adenosine 5′-triphosphate (ATP) in NaCl and KCl aqueous solutions at different ionic strengths (0 I / mol L − 1 ≤ 5 for NaCl aq , 0 I / mol L − 1 ≤ 3 for KCl aq ) and at t = 25 °C were investigated. A selection of literature data on ATP protonation constants and on activity isopiestic coefficients was performed, together with new potentiometric measurements (by ISE-H + , glass electrode). Both literature and new experimental data were used to model the dependence on ionic strength and ionic medium of ATP protonation by SIT (Specific ion Interaction Theory) and Pitzer equations. In addition to values of first and second ATP protonation constants in…
Protonation of Carbonate in Aqueous Tetraalkylammonium Salts at 25°C.
2006
Protonation constants of carbonate were determined in tetramethylammonium chloride (Me4NClaq 0.1≤I/mol kg−1 ≤4) and tetraethylammonium iodide (Et4NIaq 0.1≤I/mol kg−1 ≤1) by potentiometric ([H+]-glass electrode) measurements. Dependence of protonation constants on ionic strength was taken into account by modified specific ion interaction theory (SIT) and by Pitzer models. Literature data on the protonation of carbonate in NaClaq (0.1≤I/mol kg−1 ≤6) were also critically analysed. Both protonation constants of carbonate follow the trend Et4NI>Me4NCl > NaCl. An ion pair formation model designed to take into account the different protonation behaviours of carbonate in different supporting electr…
Supervision by the state prerogatives of french sports federations
2013
French sports federations have developed without any state intervention. They had their own prerogatives to organize competitions in their respective sporting discipline. By virtue of their association status, they were entirely governed by private law. However, following a decision taken in 1974 by the Board of State confirming the existence of a public service delegated to the federal structure, the legislation gradually devote the principle of granting their prerogatives by the Ministry of Sports through two acts: the ministerial approval and delegation of public service. Since the issuance of these acts is synonymous powers recognized federations by state law and that the delegation lea…
W sprawie zgodności z Konstytucją RP powoływania sędziów – członków Krajowej Rady Sądownictwa przez Sejm
2022
Przedmiotem niniejszego tekstu jest ustalenie, czy art. 9a ustawy o Krajowej Radzie Sądownictwa jest zgodny z Konstytucją RP. W celu udzielenia odpowiedzi na to pytanie przeanalizowano relacje, jakie powinny panować pomiędzy poszczególnymi władzami w systemie opartym o zasadę podziału władz. Następnie rozwiano wątpliwości co do tego, czy KRS jest organem występującym w pionie władzy sądowniczej. Ostatecznie stwierdzono, że w RP Sejm nie powinien mieć innych kompetencji kreacyjnych wobec organów władzy sądowniczej, niż tylko te, które wyraźnie przewiduje Konstytucja RP. W przeciwnym razie izba postawiona jest w pozycji nieuzasadnionej supremacji względem judykatywy, a władza sądownicza nie d…
Some properties of vertex-oblique graphs
2016
The type t G ( v ) of a vertex v ? V ( G ) is the ordered degree-sequence ( d 1 , ? , d d G ( v ) ) of the vertices adjacent with v , where d 1 ? ? ? d d G ( v ) . A graph G is called vertex-oblique if it contains no two vertices of the same type. In this paper we show that for reals a , b the class of vertex-oblique graphs G for which | E ( G ) | ? a | V ( G ) | + b holds is finite when a ? 1 and infinite when a ? 2 . Apart from one missing interval, it solves the following problem posed by Schreyer et?al. (2007): How many graphs of bounded average degree are vertex-oblique? Furthermore we obtain the tight upper bound on the independence and clique numbers of vertex-oblique graphs as a fun…
Heyting-valued interpretations for Constructive Set Theory
2006
AbstractWe define and investigate Heyting-valued interpretations for Constructive Zermelo–Frankel set theory (CZF). These interpretations provide models for CZF that are analogous to Boolean-valued models for ZF and to Heyting-valued models for IZF. Heyting-valued interpretations are defined here using set-generated frames and formal topologies. As applications of Heyting-valued interpretations, we present a relative consistency result and an independence proof.